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LLMs

A guide to the best B2B podcast coverage of LLMs - the shows and 18 episodes that go deepest, ranked by substance, not downloads.

Large language models are reshaping how B2B companies operate - from security implications explored by Smartsheet's CTO Cynthia Tee, to stakeholder management approaches at Capgemini, to accessibility standards championed by Moleworks' Rachael Mole. Beyond internal adoption challenges like those Descript's CEO tackled, LLMs are fundamentally altering B2B buying behavior and partnership strategies, with PartnerStack examining how AI affects distribution and trust, while simultaneously creating new vulnerabilities and content ranking dynamics that companies like those featured in recent episodes are actively navigating.

Best shows on LLMs

Best episodes on LLMs

  1. Evolving Executive Leadership with Agentic AI (Elise Neel)

    What’s the BUZZ? - AI in Business · 2026-04-18

    81 / 100

    And so instead, as we think about collaboration, these machines and LLMs by their very nature, their, inherent nature is to take this swarm complex to think about connections that.

  2. PayPal Ads’ Big Retail Media Bet: Why Shoppable Ads Could Finally Work (And The Future of Commerce in an AI World)

    Retail Media Breakfast Club · 2026-06-23

    80 / 100

    What I mean by that is that a lot of the consumer behaviors now [00:10:00] start on LLMs.

  3. How Klaviyo is Redefining B2C CRM, Services, and AI with Grant Deken, Head of Product of Klaviyo Services

    Lessons In Product Management · 2025-08-19

    80 / 100

    So I want to give you the floor and um, just kind of share like how is Genai and this whole machine learning revolution LLMs impacting Klaviyo as a business?

  4. AI Security: Patricia Titus on Shadow AI, Non-Human Identities, and AI Defense

    AI Security, Cyber Risk, and Cloud Strategy on ClearTech Loop · 2026-05-27

    79 / 100

    The LLMs, I feel like people are being a little more purposeful about those, like the agents have, like, gotten loose, like gnomes in our systems, and they are just.

  5. The Truth About The Recent Vulnerability Spike w/ Aaron Mitchell | Episode 198

    The Software Leaders Uncensored Podcast · 2026-06-09

    75 / 100

    Now with Claude and, and Codex and all of these LLMs pounding these open source libraries for, to look for vulnerabilities, that number looks like it could as much as double.

  6. #63 Throxy: The outbound company that ignored LinkedIn completely | Arnau Ayerbe

    Venturing with Vishesh · 2026-05-13

    71 / 100

    Very early from the start, you could see hints that LLMs were simply this magical thing that were going to transform the way the world looked.

  7. From Hostile to Rewired: How Descript's CEO Drives AI Adoption | Laura Burkhauser

    LaunchPod · 2026-06-16

    69 / 100

    And so when LLMs came out, first of all, we kind of got multimodal editing for free because if you think about video as a document, what are LLMs incredibly good at doing?

  8. The Machine Ate the Storefront, PayPal Mapped the Collapse

    Future Commerce · 2026-06-10

    69 / 100

    Instead what they're doing is to actually start the search on LLMs.

  9. The Truth About AI Content, SEO, and What Actually Ranks in 2026 with Kyle Roof

    Revenue Optimization with StatsDrone · 2026-04-30

    67 / 100

    Um, but the biggest thing we've actually been running a year long case study, um, we're a little bit over a year now and looking um, at kind of the base level of terms that we get out of the LLMs, like without prompting, what, what is the content that we're getting?

  10. Accessible AI Is Better Business, with Rachael Mole - Moleworks [084]

    The Business of AI · 2026-06-18

    66 / 100

    So in this respect we're talking about generative AIs and LLMs.

  11. AI, Security, and the Courage to Reinvent with Smartsheet CTO Cynthia Tee

    Shift AI Podcast · 2026-06-26

    66 / 100

    If we didn't have generative AI and LLMs, it would be, uh, just very challenging to make an easier interface.

  12. #53 Ask Me Anything

    Playing With Unicorns · 2026-03-23

    64 / 100

    In the near term, um, uh, it'll be an open cloud type agent embedded or provided by the core, um, uh, by the core marketplaces, um, sorry, the core AI LLMs like Claude or OpenAI that will offer an open cloud equivalent without any of the security concerns and risks that you're, that you're seeing today.

  13. Episode 34: Building a Better Customer Feedback Engine with Brannon Santos (Founder & CEO at ChatGems)

    The Founder's Formula Podcast · 2023-09-12

    54 / 100

    When we saw LLMs come out in popularity and usability six months ago, one of the first thoughts that I had was can I leverage the LLM to extract new insights from humans rather than asking it to go extract insights from a corpus of data

  14. Faith, The Machine Average & Staying Human in the Age of AI w/ Abhijith Ravinutala

    It's Not the End of the World: Everyday Use Cases for AI · 2026-02-27

    49 / 100
  15. How is AI changing B2B buying behavior and making partnerships more important for distribution and trust? | Bryn Jones, Co-Founder, PartnerStack

    Straight To Voicemail · 2026-06-16

    47 / 100

    But now buyers are showing up out after spending time inside of LLMs, um, community threads and conversations in areas that they already trust.

  16. Pull Up a Chair: A Conversation with Lena Redko

    Analytics Friday · 2026-05-14

    46 / 100

    It's uh, how you differentiate because LLMs are so intelligent if uh, they are not um, um elevated in some way by the human side and to give different aspects and blind spots and strategy.

  17. How Living Corporate Supported Capgemini's Stakeholder Management Strategy with AI ! Ft. Janet Pope

    Living Corporate · 2026-06-23

    45 / 100

    We have some things that we've done that are proprietary and how we, how we leverage certain LLMs.

  18. Cross-Functionally Leveraging AI for Good with Claudine Ryan, President of TalkingPoints

    The Data Cloud Podcast · 2024-06-25